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The Mega-Bomb gloves were armor pieces that Ratchet was able to collect by completing the Clank Challenge "The Ultimate Showdown." They were needed to obtain Mega-Bomb Armor.
The left glove had a small red light on the cuff where the right glove did not and had some sort of notable double cuff instead. The difference only was in the Armor menu; in-game they were the same on both sides.